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A reliable way to find the Mug Shot item is to head to the graveyard that is south of Asylum and kill the Blightfather. You will need to find the Mug Shot item to start the Character Mission. If you are still struggling with some of these unlocks, check out this video:
You can find these in set locations across the map: top of the crane at Construction Site, directly on top of the Lighthouse, in the rafters of the Turbine area, and on the rooftop of the Asylum. You'll need to find "Punching Mitts" to unlock Ruin. Finish Match with I Ching Coins in Inventory.You are looking to find the item "I Ching Coins" which will give you the mission to unlock the Recon character. This might be the hardest one, because not only do you have to win the game, you'll have to have those three perks active when you do! Recon Finish Match with Ocular Proshetic in Inventory.You can find this in Supply Drops or off fallen enemies. To start the Prophet Character Mission you will need to find the Ocular Prosthetic. This is still kind of difficult, but it's much more doable than the previous version of the mission! Prophet Now, they've changed to you just having to kill 2 enemies without taking damage from them. It was really hard to do this because you had to get lucky in the people you killed, and hoped they were using Specialist characters. This used to be that you had to kill three Specialist characters in the game. Finish Match with Juneau's Tags in Inventory.